Impacts of Methane on Carbon Dioxide Storage in Brine Formations          下载免费PDF全文

Mohamad R. Soltanian  Mohammad A. Amooie  David R. Cole  Thomas H. Darrah  David E. Graham  Susan M. Pfiffner  Tommy J. Phelps  Joachim Moortgat 《Ground water》2018,56(2):176-186

In the context of geological carbon sequestration (GCS), carbon dioxide (CO₂) is often injected into deep formations saturated with a brine that may contain dissolved light hydrocarbons, such as methane (CH₄). In this multicomponent multiphase displacement process, CO₂ competes with CH₄ in terms of dissolution, and CH₄ tends to exsolve from the aqueous into a gaseous phase. Because CH₄ has a lower viscosity than injected CO₂, CH₄ is swept up into a ‘bank’ of CH₄‐rich gas ahead of the CO₂ displacement front. On the one hand, this may provide a useful tracer signal of an approaching CO₂ front. On the other hand, the emergence of gaseous CH₄ is undesirable because it poses a leakage risk of a far more potent greenhouse gas than CO₂ if the cap rock is compromised. Open fractures or faults and wells could result in CH₄ contamination of overlying groundwater aquifers as well as surface emissions. We investigate this process through detailed numerical simulations for a large‐scale GCS pilot project (near Cranfield, Mississippi) for which a rich set of field data is available. An accurate cubic‐plus‐association equation‐of‐state is used to describe the non‐linear phase behavior of multiphase brine‐CH₄‐CO₂ mixtures, and breakthrough curves in two observation wells are used to constrain transport processes. Both field data and simulations indeed show the development of an extensive plume of CH₄‐rich (up to 90 mol%) gas as a consequence of CO₂ injection, with important implications for the risk assessment of future GCS projects.  相似文献   

Comparison of ground temperature response of energy pile and borehole heat exchanger during thermal response tests     

Jin Luo  Haifeng Zhao  Shuqiqang Gui  Wei Xiang  Joachim Rohn 《Environmental Earth Sciences》2016,75(22):1463

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Consistency of seven different GNSS global ionospheric mapping techniques during one solar cycle   总被引：1，自引：0，他引：1  

David Roma-Dollase  Manuel Hernández-Pajares  Andrzej Krankowski  Kacper Kotulak  Reza Ghoddousi-Fard  Yunbin Yuan  Zishen Li  Hongping Zhang  Chuang Shi  Cheng Wang  Joachim Feltens  Panagiotis Vergados  Attila Komjathy  Stefan Schaer  Alberto García-Rigo  José M. Gómez-Cama 《Journal of Geodesy》2018,92(6):691-706

In the context of the International GNSS Service (IGS), several IGS Ionosphere Associated Analysis Centers have developed different techniques to provide global ionospheric maps (GIMs) of vertical total electron content (VTEC) since 1998. In this paper we present a comparison of the performances of all the GIMs created in the frame of IGS. Indeed we compare the classical ones (for the ionospheric analysis centers CODE, ESA/ESOC, JPL and UPC) with the new ones (NRCAN, CAS, WHU). To assess the quality of them in fair and completely independent ways, two assessment methods are used: a direct comparison to altimeter data (VTEC-altimeter) and to the difference of slant total electron content (STEC) observed in independent ground reference stations (dSTEC-GPS). The main conclusion of this study, performed during one solar cycle, is the consistency of the results between so many different GIM techniques and implementations.  相似文献   

Interannual variability of air temperature inversions in ice-free area of northern James Ross Island,Antarctica     

Ambrožová  Klára  Láska  Kamil  Matějka  Michael  Reuder  Joachim 《Theoretical and Applied Climatology》2022,148(3-4):967-983

Theoretical and Applied Climatology - Air temperature inversions are common features in Antarctica, especially in the interior where they are observed nearly year-round. Large temporal variability...  相似文献   

Celebrating 50 years of SWIMs (Salt Water Intrusion Meetings)     

Vincent E. A. Post  Gualbert Oude Essink  Adam Szymkiewicz  Mark Bakker  Georg Houben  Emilio Custodio  Clifford Voss 《Hydrogeology Journal》2018,26(6):1767-1770

The Salt Water Intrusion Meetings, or SWIMs, are a series of meetings that focus on seawater intrusion in coastal aquifers and other salinisation processes. 2018 marks the 50th year of the SWIM and the 25th biennial meeting. The SWIM proceedings record half a century of research progress on site characterisation, geophysical and geochemical techniques, variable-density flow, modelling, and water management. The SWIM is positioning itself to remain a viable platform for discussing the coastal aquifer management challenges of the next 50 years.  相似文献   

Determination of ground thermal properties for energy piles by thermal response tests     

Jin Luo  Haifeng Zhao  Wei Huang  YongQiang Zhu  Wei Xiang  Joachim Rohn 《Environmental Earth Sciences》2018,77(4):152

Thermal properties of ground heat exchanger (GHE) such as effective thermal conductivity and borehole thermal resistance are commonly measured in the field by thermal response tests (TRTs). TRT has been proved to be a consolidated method to determine thermal properties of traditional borehole heat exchangers (BHEs). However, there is still lack of data for adopting TRT on energy piles with often a large diameter and deficiency in validation of TRT results with geological materials. In this study, ground thermal properties for typical configured GHEs of energy piles are investigated. Three TRTs are conducted and the obtained results are analyzed. Effective thermal conductivity, λ_eff, of the ground derived by following the traditional linear source model shows large deviation as compared to the thermal conductivity of the geological materials. In order to determine λ_eff properly, the linear source model is modified and an equivalent radius, r_eq, of energy piles is considered. The λ_eff estimated by the modified model shows a good agreement with thermal conductivity of the in situ geological materials. In addition, there has been no obvious correlation between borehole thermal resistances and thermal efficiency due to heat transport of energy piles that depends not only by borehole thermal resistance but also by the pile’s diameter and ground conditions. The findings drawn from this study indicate that the modified model is reasonable and useful in determining thermal properties of energy piles.  相似文献   

The Institute of Geography and Geoecology of the Academy of Sciences     

Prof.Dr. Joachim Heinzmann 《GeoJournal》1990,22(2):205-207

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Petrology of Lower Cretaceous carbonate mud mounds (Albian, N. Spain): insights into organomineralic deposits of the geological record   总被引：2，自引：0，他引：2  

Fritz Neuweiler  Pascale Gautret  Volker Thiel  Robert Lange  Walter Michaelis  & Joachim Reitner 《Sedimentology》1999,46(5):837-859

The process of organomineralization is increasingly well understood with respect to modern carbonate sediments accumulating adjacent to tropical reef atolls and reef caves. Mineralization related to non-living organic substrates results in autochthonous micrite production (‘automicrites’). ‘Automicrites’ are the main constructive element of Lower Cretaceous (Albian) carbonate mud mounds in northern Spain. These slope mud mounds occur within transgressive and early highstand system tracts encompassing several macrobenthic ecological zones. They are clearly separated from the biocalcifying carbonate factory (Urgonian carbonate platforms), in both space and time. Within these build-ups, most ‘automicrites’ were initially indurated and accreted to form a medium-relief growth framework. ‘Automicrites’ have a uniform, presumably high-Mg-calcite precursor mineralogy. They show an inorganic stable-isotope signature (?¹³C around +3·3‰) within the range of early marine cements, and skeletal compounds lacking major vital effects. Epifluorescence microscopy shows that they have facies-specific fluorescence, which is similar to skeletal compounds of Acanthochaetetes, but clearly different from allomicritic sediment and cements, which are mostly non-fluorescent. The EDTA-soluble intracrystalline organic fraction (SIOF) of Albian automicrites shows an amino acid spectrum that is similar to shallow subsurface samples from their modern counterparts. Gel electrophoresis of the SIOF demonstrates an exclusively acidic character, and a mean molecular size range between 20 and 30 kDa. Experiments in vitro (inhibition tests) indicate that the SIOF has a significant Ca²⁺-binding capacity. Fluorescence and chemical characteristics of SIOF point to a main substance class, such as humic and fulvic acids, compounds that form from pristine organic matter during early diagenesis. Biomarker analyses provide evidence for the crucial role of biodegradation by heterotrophic microorganisms, but no biomarker for cyanobacteria has been found. Primary sources of organic material should have been manifold, including major contributions by metazoans such as sponges. It is concluded that many carbonate mud mounds are essentially organomineralic in origin and that the resulting fabric of polygenetic muds (‘polymuds’) may represent ancestral metazoan reef ecosystems, which possibly originated during the Neoproterozoic.  相似文献   

BeppoSAX observations of 2-Jy lobe-dominated broad-line sources -- I. The discovery of a hard X-ray component     

Paolo Padovani  Raffaella Morganti  Joachim Siebert  Fausto Vagnetti  Andrea Cimatti 《Monthly notices of the Royal Astronomical Society》1999,304(4):829-838

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Differences in the eutrophication dynamics of Ammersee and Starnberger See (Southern Germany), reflected by the diatom succession in varve-dated sediments     

Joachim Alefs  Jens Müller 《Journal of Paleolimnology》1999,21(4):395-407

Diatom assemblages in the annually laminated sediments of two neighboring, pre-alpine lakes (Ammersee and Starnberger See, Southern Germany) were analyzed and compared year by year. Within both varve records of the last decades, the same 4-phase-succession of planktonic diatom species is preserved, consisting of 1. a dominance of Cyclotella species 2. assemblages of Fragilaria crotonensis, Asterionella formosa and Stephanodiscus minutulus 3. a mass bloom of Aulacoseira islandica, and 4. a dominance of Stephanodiscus species. This diatom sequence is considered as a model of a 'basic species sequence of eutrophication'. Time lags and differences in the duration of the phases between both lakes show evidence of an earlier start for nutrient loading in Starnberger See than in Ammersee, and a faster development to a higher trophic state level in the latter. The different reactions of the lakes are attributed to hydrological differences such as the existence or lack of a major tributary, the size of the catchment area, and the water residence time. The reconstruction of the eutrophication dynamics appears to be reliably hindcast by the inference of total phosphorus (TP) concentrations using weighted averaging regression and calibration techniques. Remarkable differences in the occurrence of some diatoms in both stratigraphies, which are not related to the general changes of the 'basic species sequence of eutrophication' model, may be due to the epilimnetic silica content (e.g. Fragilaria crotonensis) or competitive weaknesses (e.g. Tabellaria flocculosa).  相似文献